Fuel Processing Technology, Vol.92, No.4, 757-763, 2011
Fischer-Tropsch catalyst testing in a continuous bench-scale coal gasification system
A bench-scale oxygen-blown fluid-bed gasifier was coupled to a modular fixed-bed Fischer-Tropsch (FT) reactor system for testing an FT catalyst under syngas. Various blends of subbituminous coal, torrefied biomass, and untreated biomass were gasified at 22 bar absolute, 800 degrees-860 degrees C, and 4 kg/h. Syngas exiting the fluid bed passed through a cyclone, candle filter, and sulfur sorbent to reduce fine particulate and H2S to levels well below 1 ppmv. The syngas was cooled to condense out moisture and volatiles and then reheated to temperatures required for Fr synthesis. The clean syngas then flowed into the FT reactor with a 5:1 ratio of recycled Fr product gas-to-fresh syngas feed. A 70% overall conversion of CO and H-2 was achieved at 269 degrees C and 18.9 bar over an iron-based catalyst supported on gamma-alumina pellets. (C) 2010 Elsevier B.V. All rights reserved.