Synthesis and three dimensional pattern finishing properties of blocked isocyanate prepolymers

Un-Soo Lee; Hak-Yong Kim; Fan-Long Jin; Soo-Jin Park

Journal of Industrial and Engineering Chemistry, Vol.18, No.2, 792-799, March, 2012

DOI10.1016/j.jiec.2011.10.001 Export Citation

Synthesis and three dimensional pattern finishing properties of blocked isocyanate prepolymers

Un-Soo Lee, Hak-Yong Kim^{1, †}, Fan-Long Jin², and Soo-Jin Park^{3, †}

Protex Korea Co. Ltd., Jeonju 565-900, South Korea
¹Department of Textile Engineering, Chonbuk National University, Chonju 560-756, South Korea
²School of Chemical and Materials Engineering, Jilin Institute of Chemical Technology, Jilin City 132022, People’s Republic of China
³Department of Chemistry, Inha University, Nam-gu, Incheon 402-751, South Korea

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Two kinds of blocked isocyanate prepolymers (BIPs), BIP-S and BIP-H, were synthesized, and three dimensional pattern (3D) finishing properties of BIPs were investigated with several techniques. As a result, the BIP-H exhibited higher glass transition temperature, tensile strength, and tensile modulus than did BIP-S. The combination of two kinds of antioxidants resulted in good performance that prevented yellowing at high temperature and exposure to sunlight. 3D pattern finished cotton fabrics coated with BIP-S showed a higher transparency than that of non-coated cotton fabrics. Both cotton fabrics coated with BIP-S and those coated with BIP-H showed excellent repellency to alkali solution.

Keywords:Blocked isocyanate prepolymers;Viscosity;Glass transition temperature;Tensile strength;Antioxidant

[References]

Oertel G, Reichmann W, Polyurethane Handbook, Hanser Publishers (1994)
Dietrich D, Advances in Urethane Ionomer, Technomic Publishing Co. Inc. (1995)
Jiang HM, Zheng Z, Song WH, Wang XL, J. Appl. Polym. Sci., 108(6), 3644 (2008)
Kim KY, Park WL, Chung YS, Shin DG, Han JW, Carbon Lett., 12, 31 (2011)
Spyrou E, Franke R, Prog. Org. Coat., 48, 201 (2003)
Qin Q, Dai Y, Yi K, Zhang L, Ryu SK, Jin R, Carbon Lett., 11, 176 (2010)
Gao ZH, Li D, J. Appl. Polym. Sci., 104(5), 2980 (2007)
Tsai HC, Hong PD, Yen MS, Text. Res. J., 77, 710 (2007)
Schift H, Halbeisen M, Schu¨ tz U, Delahoche B, Vogelsang K, Gobrecht J, Microelectron. Eng., 83, 855 (2006)
Was-Gubala J, Sci. Justice., 49, 165 (2009)
Yang XH, Li DG, Text. Res. J., 77, 779 (2007)
Schift H, Schutz U, Gobrecht J, Microelectron. Eng., 83, 855 (2006)
Heberlein G, Weiss E, Text. Res. J., 28, 227 (1958)
Chen KS, Chen YS, Yu TL, Tsai CL, J. Polym. Res., 9, 119 (2002)
Bieleman J, Additives for Coatings, Wiley VCH (2000)
Kaffashi B, Barmar M, Eyvani J, Colloids Surf., A., 254, 125 (2005)
Lee JH, Lee US, Jeong KU, Seo YA, Park SJ, Kim HY, Polym. Int., 59, 1683 (2010)
Xu HJ, Jin FL, Park SJ, Bull. Korean Chem. Soc., 30, 2643 (2009)
Bang HJ, Kim HY, Jin FL, Park SJ, Bull. Korean Chem. Soc., 32, 541 (2011)
Gnanarajan TP, Nasar AS, Radhakrishnan G, Eur. Polym. J., 38, 487 (2002)
Kelen T, Library of Congress Catalogue (1982)
Zhang LN, Ruan D, Zhou JP, Ind. Eng. Chem. Res., 40(25), 5923 (2001)
Chan CK, Jiang XY, Lau MP, J. Mater. Process. Technol., 174, 183 (2006)
Ji F, Li R, Qiu Y, Text. Res. J., 76, 12 (2006)

[Referenced By]

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[1] Oertel G, Reichmann W, Polyurethane Handbook, Hanser Publishers (1994)

[2] Dietrich D, Advances in Urethane Ionomer, Technomic Publishing Co. Inc. (1995)

[3] Jiang HM, Zheng Z, Song WH, Wang XL, J. Appl. Polym. Sci., 108(6), 3644 (2008)

[4] Kim KY, Park WL, Chung YS, Shin DG, Han JW, Carbon Lett., 12, 31 (2011)

[5] Spyrou E, Franke R, Prog. Org. Coat., 48, 201 (2003)

[6] Qin Q, Dai Y, Yi K, Zhang L, Ryu SK, Jin R, Carbon Lett., 11, 176 (2010)

[7] Gao ZH, Li D, J. Appl. Polym. Sci., 104(5), 2980 (2007)

[8] Tsai HC, Hong PD, Yen MS, Text. Res. J., 77, 710 (2007)

[9] Schift H, Halbeisen M, Schu¨ tz U, Delahoche B, Vogelsang K, Gobrecht J, Microelectron. Eng., 83, 855 (2006)

[10] Was-Gubala J, Sci. Justice., 49, 165 (2009)

[11] Yang XH, Li DG, Text. Res. J., 77, 779 (2007)

[12] Schift H, Schutz U, Gobrecht J, Microelectron. Eng., 83, 855 (2006)

[13] Heberlein G, Weiss E, Text. Res. J., 28, 227 (1958)

[14] Chen KS, Chen YS, Yu TL, Tsai CL, J. Polym. Res., 9, 119 (2002)

[15] Bieleman J, Additives for Coatings, Wiley VCH (2000)

[16] Kaffashi B, Barmar M, Eyvani J, Colloids Surf., A., 254, 125 (2005)

[17] Lee JH, Lee US, Jeong KU, Seo YA, Park SJ, Kim HY, Polym. Int., 59, 1683 (2010)

[18] Xu HJ, Jin FL, Park SJ, Bull. Korean Chem. Soc., 30, 2643 (2009)

[19] Bang HJ, Kim HY, Jin FL, Park SJ, Bull. Korean Chem. Soc., 32, 541 (2011)

[20] Gnanarajan TP, Nasar AS, Radhakrishnan G, Eur. Polym. J., 38, 487 (2002)

[21] Kelen T, Library of Congress Catalogue (1982)

[22] Zhang LN, Ruan D, Zhou JP, Ind. Eng. Chem. Res., 40(25), 5923 (2001)

[23] Chan CK, Jiang XY, Lau MP, J. Mater. Process. Technol., 174, 183 (2006)

[24] Ji F, Li R, Qiu Y, Text. Res. J., 76, 12 (2006)