A novel intelligent humidity control composite material with excellent humidity control performances has been prepared, comprising a natural polymer derivative (carboxymethyl cellulose (CMC)), a porous natural mineral (sepiolite), and an acrylic acid (AA)/acrylamide (AM) copolymer. It features high moisture adsorption capacity, fast response to humidity changes, small equilibrium humidity control range and good acid gas absorbability. It is suitable for maintaining a proper micro-environment for places such as museums or galleries. The appearance and structural properties of the resultant material have been investigated by scanning electronic microscope (SEM), Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD). The humidity control performances of the material at certain relative humidity (RH) and changed absolute humidity (AH) have been measured. The adsorption capabilities of the material for sulphur dioxide and nitrogen dioxide have also been investigated in this study. The results reveal that the material maintains a relative humidity in the 57-60.5% range at 25 degrees C, and reaches the equilibrium levels within 3.5 h. It is worth noting that the composite material shows an excellent humidity buffering effect at changed AH and temperatures. The equilibrium moisture adsorption amount is 78.6% of its own weight. The adsorption capacities for nitrogen dioxide and sulphur dioxide are 227 mg g(-1) and 288 mg g(-1), respectively. (C) 2010 Elsevier B.V. All rights reserved.