Electrochimica Acta, Vol.56, No.14, 5184-5188, 2011
Semiconducting polymer-incorporated nanocrystalline TiO2 particles for photovoltaic applications
In this work, we study hybrid solar cells based on blends of the semiconducting polymer poly(3-octylthiophene-2,5-diyl)(P3OT) and [6,6]-phenyl C-61 butyric acid methyl (PCBM) coated titanium dioxide (TiO2) nanocrystal film. The Fourier transform infrared spectra (FTIR). UV-vis absorption spectra and PL quenching researches show that the films had a stronger absorption in visible light range. The influence of the PCBM:P3OT ratio were researched and the optimized ratio of PCBM to P3OT (1:1.5) exhibit a short circuit current of 4.42 mA cm(-2), an open circuit voltage of 0.81 V, a fill factor of 0.73 and a light-to-electric conversion efficiency of 2.61% under a simulated solar light irradiation of 100 mW cm(-2). (C) 2011 Elsevier Ltd. All rights reserved.
Keywords:Heterojunction;Poly(3-octylthiophene-2,5-diyl)[6,6]-Phenyl-C-61-butyric acid methyl ester;TiO2 nanocrystal;Solar cell