This study examines the ability of chemometrics methods, namely multivariate image analysis (MIA) and Grey Level Co-occurrence Matrix analysis (GLCM), to extract meaningful information from visible and near-infrared spectral images of extruded wood/plastic composite materials for predicting spatio-temporal variations in their properties. The samples were produced under varying process and feed conditions according to designed experiments. Mechanical properties of the samples were measured using standard analytical methods both during steady-state and dynamic transition periods. A Bootstrap-PLS regression technique was first used for selecting the spectral bands (i.e. wavelengths) that were the most highly correlated with the material properties. In a second step, a more parsimonious PLS regression model was built between the spectral and textural features extracted from the lower dimensional spectral images and the corresponding quality properties of each sample. The imaging sensor was able to simultaneously monitor 7 properties in both steady-state operation and during transitions. (C) 2010 Elsevier Ltd. All rights reserved.