Preparation of Tunable Emissive Poly(ethylene oxide) Nanofibers by Doping with TPP and DCM

Lianji Zhang; Dongri Zhang; Sumei Zhan; Peipei Yang; Guixia Yang; Zonghao Huang; Youn-Sik Lee

Macromolecular Research, Vol.20, No.2, 212-215, February, 2012

DOI10.1007/s13233-012-0024-3 Export Citation

Preparation of Tunable Emissive Poly(ethylene oxide) Nanofibers by Doping with TPP and DCM

Lianji Zhang^{1, 2}, Dongri Zhang³, Sumei Zhan^{1, 4}, Peipei Yang^{1, 4}, Guixia Yang^{1, 4}, Zonghao Huang^{1, 4, †}, and Youn-Sik Lee⁵

¹School of Chemistry, Northeast Normal University, Changchun, 130024, P. R. China
²Department of Chemistry, College of Science, Yanbian University, Yanji, 133002, P. R. China
³Department of Chemical Engineering, College of Engineering, Yanbian University, Yanji, 133002, P. R. China
⁴, China
⁵Division of Chemical Engineering, Chonbuk National University, Jeonbuk, 561-756, Korea

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Poly(ethylene oxide) (PEO) nanofibers that were doubly-doped with a donor, 1,3,5-triphenyl-2-pyrzoline (TPP), and an acceptor, 4-(dicyanomethylene)-2-methyl-6-(p-dimethyl-aminostyryl)-4H-pyran (DCM), were prepared by electrospinning to be 200-300 nm in diameter. Fluorescence from DCM was caused by non-radiative Forster-type fluorescence resonance energy transfer from photo-excited TPP to DCM. The color of the fluorescence from the PEO-TPP/DCM nanofibers was controllable through variation of the TPP:DCM molar ratio and ranged from blue to orange to white.

Keywords:poly(ethylene oxide) (PEO);1,3,5-triphenyl-2-pyrzoline;DCM;tunable emissive nanofiber;electrospinning.

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[1] Ner Y, Grote JG, Stuart JA, Sotzing GA, Angew.Chem. Int. Ed., 48, 5134 (2009)

[2] Lee KJ, Oh JH, Kim Y, Jang J, Adv. Mater., 18(17), 2216 (2006)

[3] Zhang H, Song H, Dong B, Han L, Pan G, Bai X, Fan L, Lu S, Zhao H, Wang F, J. Phys. Chem. C., 112, 9155 (2008)

[4] Moran-Mirabal JM, Slinker JD, DeFranco JA, Verbridge SS, Ilic R, Flores-Torres S, Abruna H, Malliaras GG, Craighead HG, Nano Lett., 7, 458 (2007)

[5] Yang P, Zhan S, Huang Z, Zhai J, Wang D, Xin Y, Zhang L, Sun M, Shao C, Mater. Lett., 65, 537 (2011)

[6] Yang PP, Chen JF, Huang ZH, Zhan SM, Jiang ZJ, Qiu YQ, Shao C, Mater. Lett., 63, 1978 (2009)

[7] Reneker DH, Yarin AL, Polymer, 49(10), 2387 (2008)

[8] Antaya H, Richard-Lacroix M, Pellerin C, Macromolecules, 43(11), 4986 (2010)

[9] Huang ZM, Zhang YZ, Kotaki M, Ramakrishna S, Compos. Sci. Technol., 63, 2223 (2003)

[10] Wang C, Yan E, Li G, Sun Z, Wang S, Tong Y, Li W , Xin Y, Huang Z, Yan P, Synth. Met., 160, 1382 (2010)

[11] Anni M, Manna L, Cingolani R, Valerini D, Creti A, Omascolo ML, Appl. Phys. Lett., 85, 4169 (2004)

[12] Dong B, Song H, Yu H, Zhang H, Qin R, Bai X, Pan G, Lu S, Wang F, Fan L, Dai Q, J. Phys. Chem., C., 112, 1435 (2008)

[13] Xin Y, Huang Z, Li W, Jiang Z, Tong Y, Wang C, Eur.Polym. J., 44, 1040 (2008)

[14] Zhao Q, Huang Z, Wang C, Zhao Q, Sun H, Wang D, Mater. Lett., 61, 2159 (2007)

[15] Peng AD, Xiao DB, Ma Y, Yang WS, Yao JN, Adv. Mater., 17(17), 2070 (2005)

[16] Zhao YS, Fu HB, Hu FQ, Peng AD, Yang WS, Yao JN, Adv. Mater., 20(1), 79 (2008)

[17] Zhong GY, He J, Zhang ST, Xu Z, Xiong ZH, Shi HZ, Ding XM, Huang W, Hou XY, Appl. Phys. Lett., 80, 4846 (2002)

[18] Sandler SR, Tsou KC, J. Chem. Phys., 39, 1062 (1963)

[19] Dahne L, Biller E, Adv. Mater., 10(3), 241 (1998)

[20] Felorzabihi N, Froimowicz P, Haley JC, Bardajee GR, Li BX, Bovero E, van Veggel FCJA, Winnik MA, J. Phys. Chem. B, 113(8), 2262 (2009)

[21] Nakabayashi T, Islam MS, Ohta N, J. Phys. Chem. B, 114(46), 15254 (2010)