화학공학소재연구정보센터
Chemistry Letters, Vol.40, No.2, 196-197, 2011
Formation of a Unique Fluorosilene-KF Complex Bearing Bulky Substituents
We report here the attempted synthesis of a stable 1-fluoro-2-hydrosilene bearing a Bpq group, which is a bulky aryl group bearing a cavity-shaped framework. We have successfully synthesized an overcrowded benzyldifluorosilane as a precursor. Treatment of the benzyldifluorosilane with 2 equiv of t-BuOK in THF afforded the corresponding benzyl anion, the structure of which showed a unique feature as a fluorosilene-KF complex.