Polymer(Korea), Vol.35, No.6, 553-557, November, 2011
전기방사법을 이용한 폴리(비닐 알코올)/수분산 폴리우레탄/몬모릴로나이트 나노복합섬유의 제조 및 특성분석
Electrospinning Fabrication and Characterization of Poly(vinyl alcohol)/Waterborne Polyurethane/Montmorillonite Nanocomposite Nanofibers
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초록
전기방사법을 이용하여 폴리(비닐 알코올)(poly(vinyl alcohol), PVA)/수분산 폴리우레탄(waterborne polyurethane, WBPU)/montmorillonite clay(MMT) 나노복합섬유를 제조하고 특성을 분석하였다. Scanning electron microscopy(SEM), transmission electron microscopy(TEM), X선 회절, thermal gravimetric analyzer(TGA) 의 분석장비들을 이용하여 제조된 나노복합섬유의 형태와 구조적, 열적특성을 확인한 결과, 평균직경이 600∼900nm인 나노복합섬유들이 성공적으로 제조되었으며, MMT가 나노섬유 내에 완전박리되어 기존의 고분자 나노섬유에 비해 열적성질이 향상되었음을 확인할 수 있었다. 본 연구를 통해 제조된 나노복합섬유는 친수성이고 생체친화적인 재료들을 이용하여 제조되었으며, 의료 분야를 비롯하여 의류 및 산업용 코팅제, 필터 등의 분야로 이용이 가능할 것으로 보인다.
Poly(vinyl alcohol) (PVA)/waterborne polyurethane (WBPU)/montmorillonite clay (MMT) nanocomposite nanofibers were prepared using electrospinning technique of aqueous solutions. Scanning electron microscopy, transmission electron microscopy, X-ray diffraction and thermal gravimetric analyzer were used to characterize the morphology and properties of the nanocomposite nanofibers. Since PVA, WBPU and MMT are hydrophilic, non-toxic and biocompatible materials, these nanocomposite nanofibers can be used for filter and medical industries as wound dressing materials, antimicrobial filters, etc.
Keywords:poly(vinyl alcohol)(PVA);waterborne polyurethane(WBPU);montmorillonite(MMT);nanocomposite;nanofiber.
- Li L, Bellan LM, Craighead HG, Frey MW, Polymer, 47(17), 6208 (2006)
- Feng SS, Mei L, Anitha P, Gan CW, Zhou W, Biomaterials., 30, 3297 (2009)
- Kwon SY, Cho EH, Kim SS, J. Biomed. Mater.Res. Part B: Appl. Biometer., 83, 276 (2007)
- Angellier-Coussy H, Torres-Giner S, Morel MH, Gontard N, Gastaldi E, J. Appl. Polym. Sci., 107(1), 487 (2008)
- Park HB, Lee YM, J. Membr. Sci., 197(1-2), 283 (2002)
- Abraham GA, Queiroz AAA, Roman JS, Biomaterials., 22, 1971 (2001)
- Rockwood DN, Akins RE, Parrag IC, Woodhousw KA, Biomaterials., 29, 4783 (2008)
- Yang CH, Yang HJ, Wen TC, Wu MS, Chang JS, Polymer, 40(4), 871 (1999)
- Huybrechts J, Bruylants P, Vaes A, De MA, Prog. Org. Coat., 38, 67 (2000)
- Reneker DH, Chun I, Nanotechnology., 7, 216 (1996)
- Li D, Xia YN, Adv. Mater., 16(14), 1151 (2004)
- Min BM, Lee G, Kim SH, Nam YS, Lee TS, Park WH, Biomaterials., 25, 1289 (2004)
- Sangamesh GK, Syam PK, Roshan J, Hogan MV, Laurencin CT, Recent Patents Biomed. Eng., 1, 68 (2008)
- Agarwal S, Wendorff JH, Greiner A, Polymer, 49(26), 5603 (2008)
- Lee HW, Karim MR, Park JH, Do Ghim H, Choi JH, Kim K, Deng YL, Yeum JH, J. Appl. Polym. Sci., 111(1), 132 (2009)
- Lee HW, Karim MR, Park JH, Bae DG, Oh W, Cheong IW, Yeum JH, Polym. Polym. Compos., 17, 47 (2009)
- Lee HW, Karim MR, Ji HM, Choi JH, Do Ghim H, Park SM, Oh W, Yeum JH, J. Appl. Polym. Sci., 113(3), 1860 (2009)
- Karim MR, Lee HW, Kim R, Ji BC, Cho JW, Son TW, Oh W, Yeum JH, Carbohydr. Polym., 78, 336 (2009)
- Park JH, Lee HW, Chae DK, Oh W, Yun JD, Deng Y, Yeum JH, Colloid Polym. Sci., 287, 943 (2009)
- Ji HM, Lee HW, Karim MR, Cheong IW, Bae EA, Kim TH, Islam MS, Ji BC, Yeum JH, Colloid Polym. Sci., 287, 751 (2009)
- Park JH, Karim MR, Kim IK, Cheong IW, Kim JW, Cho JW, Yeum JH, Colloid Polym. Sci., 288, 115 (2010)
- Yang JH, Yoon NS, Park JH, Kim IK, Cheong IW, Deng Y, Oh W, Yeum JH, J. Appl. Polym. Sci., 120, 2337 (2011)
- Barber GD, Calhoun BH, Moore RB, Polymer, 46(17), 6706 (2005)
- Zhu JJ, Wang XL, Tao FF, Xue G, Chen TH, Sun PC, Jin QH, Ding DT, Polymer, 48(26), 7590 (2007)