화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Macromolecular Research, Vol.19, No.10, 1048-1055, October, 2011
DOI10.1007/s13233-011-1008-4  Export Citation
Emulsifier-Free Synthesis of Crosslinkable ABA Triblock Copolymer Nanoparticles via AGET ATRP
Chuanjie Cheng†, Quanlei Fu, Zhongbin Liu, Liang Shen†, Yongluo Qiao, and Changqing Fu
  • Jiangxi Key Laboratory of Organic Chemistry, Jiangxi Science & Technology Normal University, Fenglin Street, Nanchang, Jiangxi, 330013, PR China
E-mail:,
A crosslinkable ABA triblock copolymer was synthesized from allylic methacrylate (AMA) monomer using a poly(ethylene oxide)-based macromolecule as both an initiator and emulsifier. The “two-step” controlled/living radical polymerization can be conducted via activator generated by electron transfer (AGET) atom transfer radical polymerization (ATRP). Cheap and commercially available N,N-dimethyldodecylamine (DMDA) was found to be a good ligand for the AGET ATRP reaction. The linear ABA triblock copolymer that contains pendent allylic groups can undergo crosslinking under UV irradiation conditions, which indicates that the environmentally friendly method has potential applications in UV curing coatings and UV curing inks, etc..
Keywords:atom transfer radical polymerization (ATRP);emulsifier-free;allylic methacrylate;triblock copolymer;UV curing.
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