화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.28, No.12, 2287-2292, December, 2011
Synthesis of biodiesel from an oil fraction separated from food waste leachate
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Biodiesel was produced from an oil fraction separated from food waste leachate, using a batch reactor system, to evaluate its potential as a renewable energy source for the first time. In order to reduce the free fatty acid content of the leachate oil fraction, three different acid catalysts, H2SO4, zeolite and Amberlyst-15, were used in the pretreatment process. The residual oil fraction after pretreatment was further treated over KOH as a base catalyst to produce a fatty acid methyl ester (FAME). The FAME content in the product was analyzed using GC/MS. A large number of different FAMEs were detected, which is characteristic of the food-waste-derived raw material used in this study. The FAME content of the product was highest when pretreated over Amberlyst-15, followed by trans-esterification. Additional refining and process optimization would be expected to further increase the FAME content. Therefore, it was concluded that the production of biodiesel from the oil fraction separated from food waste leachate is promising.
  1. Heo HS, Kim SG, Jeong KE, Jeon JK, Park SH, Kim JM, Kim SS, Park YK, Bioresour. Technol., 102, 3952 (2011)
  2. Chung KH, J. Ind. Eng. Chem., 16(4), 506 (2010)
  3. Lee SB, Han KH, Lee JD, Hong IK, J. Ind. Eng. Chem., 16(6), 1006 (2010)
  4. Uma BH, Kim YS, J. Ind. Eng. Chem., 15(1), 1 (2009)
  5. Egues I, Gonzalez Alriols M, Herseczki Z, Marton G, Labidi J, J. Ind. Eng. Chem., 16, 239 (2010)
  6. Supamathanon N, Wittayakun J, Prayoonpokarach S, J. Ind. Eng. Chem., 17(2), 182 (2011)
  7. Simasatitkul L, Siricharnsakunchai P, Patcharavorachot Y, Assabumrungrat S, Arpornwichanop A, Korean J. Chem. Eng., 28(3), 649 (2011)
  8. Park JY, Lee JS, Wang ZM, Kim DK, Korean J. Chem. Eng., 27, 1795 (2010)
  9. Jeon DJ, Yeom SH, Korean J. Chem. Eng., 27(5), 1555 (2010)
  10. Park PS, Lee SD, Korean J. Int. Agri., 20, 278 (2008)
  11. Murugesan A, Umarani C, Chinnusamy TR, Krishnan M, Subramanian R, Neduzchezhain N, Renew. Sust. Energy Rev., 13, 825 (2009)
  12. Lee JS, News Inform. Chem. Eng., 25, 613 (2007)
  13. Meher LC, Sagar DV, Naik SN, Renew. Sust. Energy Rev., 10, 248 (2006)
  14. Lee JS, Park SC, Korean Chem. Eng. Res., 48(1), 10 (2010)
  15. Zabeti M, Daud WMAW, Aroua MK, Fuel Process. Technol., 90(6), 770 (2009)
  16. Russbueldt BME, Hoelderich WF, Appl. Catal. A: Gen., 362(1-2), 47 (2009)
  17. Kim YJ, Kim DK, Rhee YW, Park SC, Lee JS, Korean Chem. Eng. Res., 41, 621 (2005)
  18. Park JY, Kim DK, Lee JS, Bioresour. Technol., 101, S62 (2010)
  19. Pappu VKS, Yanez AJ, Peerebom L, Muller E, Lira CT, Miller DJ, Bioresour. Technol., 102, 4270 (2011)
  20. Carma AC, de Souza LKC, da Costa CEF, Longo E, Zamian JR, da Rocha Filho GN, Fuel., 88, 461 (2009)
  21. Shu Q, Yang B, Yuan H, Qing S, Zhu G, Catal. Commun., 8, 2159 (2007)