Inorganic Chemistry, Vol.36, No.6, 960-961, 1997
Ligand-Exchange and Molecular Aggregation of an Ag-Sn Heterobimetallic Complex - First Structural Characterization of an Ag-Sn Bond
A direct Ag-Sn bond has been established for the first time by X-ray crystallography for the dimeric complex [MeSi{SiMe(2)N(p-Tol)}3SnAg](2) (4) [d(Ag-Sn)=2.6567(7) Angstrom], which is the product of a phosphine ligand redistribution reaction of MeSi{SiMe(2)N(p-Tol)}3SnAg(PPh(3)) (2)