In this work supercritical drying technology is investigated as a new method contrast with the conventional drying techniques to obtain La modified ceria-zirconia solid solution (CZL) with advanced textural/structural properties and its supported Pd-only three-way catalysts (TWCs) were also prepared and studied The results demonstrate that the CZL sample prepared by supercritical drying method shows relatively larger specific surface area better thermal stability and higher,redox properties as well as the prominent oxygen storage capacity compared with samples prepared by conventional drying method Moreover it also exhibits remarkable porosity and wide pore size distribution due to the elimination of vapor-liquid interface in the process of supercritical drying which is beneficial to the adsorption/desorption of pollutant in TWCs The excellent structural/textural properties of the forenamed CZL support lead to the outstanding catalytic activity wide air-to-fuel operation window of the corresponding three-way catalyst indicating its tremendous potential possibilities' Crown Copyright (C) 2010 Published by Elsevier B V All rights reserved