Self-decontaminating photocatalytic textiles functionalized by the layer-by-layer approach with high aspect ratio WO3-modified titanate nanotubes have been developed and successfully used under solar light illumination for the photocatalytic degradation of organophosphorous and organosulfide chemical weapon agents. This multilayer building method, unlike both dipping and spray techniques, has been efficiently applied to textile substrates using polyethyleneimine as counter polyelectrolyte for homogeneously functionalizing textiles by a thin layer of a dense network of entangled WO3-modified titanate nanotubes, and preparing self-decontaminating photocatalytic textiles highly efficient toward the removal under solar light of the yperite blister live agent and of dimethylmethylphosphonate as neurotoxic agent simulant. Solar light responsive high surface WO3-modified titanate nanotubes were synthesized by hydro-thermally treating TiO2 powder, with tungstate salt impregnation prior to the final calcination step. (C) 2010 Elsevier B.V. All rights reserved.