This paper describes control of the coating layer thickness and the crystallite size of the core-shell hybrid particles by controlling the process parameter. The core-shell hybrid particles were prepared using liquid phase deposition (LPD). We confirmed that the homogeneous coating was attained from the result of the zeta potential and the transmission electron microscope (TEM) observation. Furthermore, the coating layer microstructure was estimated using Brunauer-Emmett-Teller (BET) method. The obtained coating layer of titania was estimated using the band gap energy. Results indicate that the blue shift of the band gap energy signifies that the physical property of the hybrid particles was controlled by the coating layer thickness and the crystallite size, which are determined by the processing parameters. (c) 2010 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.