Synthesis of copper exchanged heteropolyacids supported on MCM-48 and its application for CO2 adsorption

Margandan Bhagiyalakshmi; Pushparaj Hemalatha; Mani Ganesh; Mei Mei Peng; Hyun Tae Jang

Journal of Industrial and Engineering Chemistry, Vol.17, No.3, 628-632, May, 2011

DOI10.1016/j.jiec.2011.05.010 Export Citation

Synthesis of copper exchanged heteropolyacids supported on MCM-48 and its application for CO2 adsorption

Margandan Bhagiyalakshmi, Pushparaj Hemalatha, Mani Ganesh, Mei Mei Peng, and Hyun Tae Jang^†

Chemical Engineering Department, Hanseo University, Seosan 360-706, South Korea

E-mail:

Copper-encapsulated heteropolyacid-impregnated mesoporous MCM-48 (Cu-HPA-MCM-48) with copper in a reduced state was synthesized, and the CO2 adsorption capacity was monitored. The synthesized material was characterized by XRD, N2 adsorption-desorption, FT-IR, DSC, CO2-TPD and XPS. The low angle X-ray diffraction pattern of the Cu-HPA-MCM-48 demonstrates the encapsulation of copper inside the pore by the disappearance of higher-order peaks. This result is further supported by the presence of Cu2p3 andW4f peaks in XPS. The CO2 adsorption capacity of Cu-HPA-MCM-48was 70 mg/g at 25 ℃ . The energy of desorption and the heat of the reaction (DHr) were 21.2 kJ/mol and 490 Btu/lb, respectively, as determined by CO2-TPD and DSC. As the DHr value of Cu-HPA-MCM-48 approaches the CO2 benchmark value (580 Btu/lb), the catalyst exhibited improved CO2 capturing capacity.

Keywords:MCM-48;HPA;Copper oxide;Encapsulation;CO2 adsorption

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[2] Yang H, Xu Z, Fan M, Gupta R, Slimane RB, Bland AE, Wright I, J. Environ. Sci., 20, 14 (2008)

[3] Ding Y, Alpay E, Chem. Eng. Sci., 55(17), 3461 (2000)

[4] Devadas M, Ramalingam B, Ramesh K, Tasrif M, Sharrat P, 21st International Symposium on Chemical Reaction Engineering, June 13.16, 2010, Philadelphia, USA (2010)

[5] Feng B, An H, Tan E, Energy Fuels, 21(2), 426 (2007)

[6] Wang XP, Yu JJ, Cheng J, Hao ZP, Xu ZP, Environ. Sci. Technol., 42, 614 (2008)

[7] Lee KB, Beaver MG, Caram HS, Sircar S, Ind. Eng. Chem. Res., 47(21), 8048 (2008)

[8] Goj A, Sholl DS, Akten ED, Kohen D, J. Phys. Chem. B, 106(33), 8367 (2002)

[9] Cavenati S, Grande CA, Rodrigues AE, J. Chem. Eng. Data., 49, 1095 (2004)

[10] Akten ED, Siriwardane R, Sholl DS, Energy Fuels, 17(4), 977 (2003)

[11] Belmabkhout Y, Pirngruber G, Jolimaitre E, Methivier AA, Adsorption., 13, 341 (2007)

[12] Himeno S, Komatsu T, Fujita S, J. Chem. Eng. Data., 50, 369 (2005)

[13] Millward AR, Yaghi OM, J. Am. Chem. Soc., 127(51), 17998 (2005)

[14] Bourrelly S, Llewellyn PL, Serre C, Millange F, Loiseau T, Ferey G, J. Am. Chem. Soc., 127(39), 13519 (2005)

[15] Yang Q, Zhong C, Chen JF, J. Phys. Chem. C., 112, 1562 (2008)

[16] Harlick PJE, Sayari A, Ind. Eng. Chem. Res., 46(2), 446 (2007)

[17] Hicks JC, Drese JH, Fauth DJ, Gray ML, Qi GG, Jones CW, J. Am. Chem. Soc., 130(10), 2902 (2008)

[18] Xu XC, Song CS, Miller BG, Scaroni AW, Ind. Eng. Chem. Res., 44(21), 8113 (2005)

[19] Song HK, Cho KW, Lee KH, J. Non-Cryst. Solids., 242, 69 (1998)

[20] Hughes RW, Lu D, Anthony EJ, Wu YH, Ind. Eng. Chem. Res., 43(18), 5529 (2004)

[21] Reddy EP, Smirniotis PG, J. Phys. Chem. B, 108(23), 7794 (2004)

[22] Yong Z, Mata V, Rodrigues AE, Sep. Purif. Rev., 26, 195 (2002)

[23] Auroux A, Gervasini A, J. Phys. Chem., 94, 6371 (1990)

[24] Kim BJ, Cho KS, Park SJ, J. Colloid Interface Sci., 342(2), 575 (2010)

[25] Hadenfeldt S, Benndorf C, Stricker A, To¨we M, Surf. Sci., 352, 295 (1996)

[26] Pohl M, Otto A, Surf. Sci., 406, 125 (1998)

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[28] Appel AM, Newell R, DuBois DL, DuBois MR, Inorg. Chem., 44(9), 3046 (2005)

[29] Angamuthu R, Byers P, Lutz M, Spek AL, Bouwman E, Science., 327, 313 (2010)

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[34] Kruk M, Jaroniec M, Pena ML, Rey F, Chem. Mater., 14, 4434 (2002)

[35] Huang HY, Yang RT, Chinn D, Munson CL, Ind. Eng. Chem. Res., 42(12), 2427 (2003)

[36] Kim S, Ida J, Guliants VV, Lin JYS, J. Phys. Chem. B, 109(13), 6287 (2005)

[37] Gargiulo N, Caputo D, Colella C, Stud. Surf. Sci. Catal., 170, 1938 (2007)

[38] Kresge CT, Leonowicz ME, Roth WJ, Vartuli JC, Beck JS, Nature., 359, 1992 (710)

[39] Bhagiyalakshmi M, Yun LJ, Anuradha R, Jang HT, J. Hazard. Mater., 175(1-3), 928 (2010)

[40] Tan Y, Xue X, Peng Q, Zhao H, Wang T, Li Y, Nano Lett., 7, 3723 (2007)

[41] Du D, Lan Y, Wang X, Shao K, Wang H, Su Z, Solid State Sci., 12, 128 (2010)

[42] Endud S, Wong KL, Micropor. Mesopor. Mater., 101, 256 (2007)

[43] Shaheen WM, Selim MM, Thermochim. Acta, 322(2), 117 (1998)

[44] Wang GC, Jiang L, Morikawa Y, Nakamura J, Cai ZS, Pan YM, Zhao XZ, Surf.Sci., 570, 205 (2004)

[45] Funk S, Hokkanen B, Wang J, Burghaus U, Bozzolo G, Garce´ s JE, Surf. Sci., 600, 583 (2006)

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[47] Dennis JS, Scott SA, Fuel., 89, 1623 (2010)