The novel inimer-containing fluorene units was successfully synthesized and characterized. Hyperbranched homopolymer and copolymers with methyl methacrylate (MMA) were prepared by the novel inimer via atom transfer radical polymerization where CuBr/1,1,4,7,10,10-hexamethyltriethylenetetramine (HMTETA) were used as catalyst. The copolymerization of inimer and MMA was performed under different ratio of the initial inimer/MMA and the inimer acted as not only the branched point (BP) but also the functional groups which emit blue light. The number-average molecular weight (M (n)) and polydispersity index (PDI) of polymers are in the ranges (3.6-18.4) x 10(3) and (1.3-2.8), respectively. Thermal gravimetric analysis (TGA) results showed all polymers had good thermal stabilities. The number of the inimers acted as branched point in the copolymer backbone is estimated by H-1 NMR spectra and UV-Vis absorption spectra.