N-[Salicylidene-1,2-ethanediaminoethyl]-2-bromoisobutyramide (SEB) was synthesized and characterized by elemental analysis, FT-IR and H-1 NMR. It had been successfully used as a bidentate initiator for the atom transfer radical polymerization (ATRP) of methyl methacrylate with CuBr/2,2'-bipyridine as the catalyst and N,N-dimethylformamide as the solvent at 70 A degrees C. The kinetics was first order in monomer and the number-average molecular weight of the polymer increased linearly with monomer conversion, indicating the 'living'/controlled nature of the polymerization. The polymerization reached high conversions producing polymers with a low molecular weight distribution (M (w)/M (n) = 1.34). The obtained poly(methylmethacrylate) (PMMA) functionalized with salicylidene-1,2-ethanediaminoethyl and omega-Br as the end groups were characterized by FT-IR spectroscopy. They can be used as macroinitiators for chain-extension reaction. Then, PMMA coatings were grafted from copper substrates by surface-initiated ATRP from a surface-bound SEB initiator. The electrochemical impedance spectroscopy measurements and potentiodynamic electrochemical experiments confirmed the successful grafting of the polymer coatings. Greatly improved short-term anticorrosive properties for PMMA modified electrodes were demonstrated by substantially increased resistance of the film for a period of 24 h as compared to bare copper.