화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Clean Technology, Vol.17, No.1, 56-61, March, 2011
Export Citation
감압잔사유 수첨분해반응의 생성물 분석방법 비교
Comparison of Analytical Methods of Products in Hydrocracking of Vacuum Residue
권혁민, 김한나, 웬후이친, 김도경1, 김도완1, 오승훈1, 신은우†
  • 울산대학교 생명화학공학부, 680-749 울산광역시 남구 대학로 93
  • 1SK에너지기술원 촉매 Lab, 305-712 대전광역시 유성구 원촌동 엑스포로 221
Hyukmin Kweon, Hanna Kim, Chinh Nguyen Huy, Do Kyong Kim1, Do-Woan Kim1, Seung Hoon Oh1, and Eun Woo Shin†
  • School of Chemical Engineering and Bioengineering, University of Ulsan, Daehakro 93, Nam-gu, Ulsan 680-749, Korea
  • 1Catalyst Lab, SK Energy Institute of Technology, Exporo 325, Yuseong-gu, Daejon 305-712, Korea
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초록
감압잔사유를 고압 회분식 반응기에 넣고，상용 Ni-Mo/Al2O3 촉매를 이용하여 450℃ , 500 ℃ 에서 수첨분해하였다. 그리고 반응 생성물을 단증류 혹은 GC-SIMDIS 방법으로 각각 분석하였다. 먼저 수첨분해반응에서는 두 온도 조건 모두 촉매 반응 뿐만 아니라 열분해 반응도 같이 일어나고 있음을 확인하였고，온도가 증가할수록 전환율이 증가하고，생성물 중 가솔린 및 납사 비율이 높아졌다. 생성물 분석 결과，500 ℃ 반응에서는 단증류와 GC-SIMDIS 분석 결과의 차이가 없었지만，450 ℃ 반응에서는 단증류에서는디젤이，GC-SIMDIS에서는 vacuum gas oil이 주 생성물로 드러났다. 이는 450 ℃ 반응에서의 단증류 분석은 단증류에 의한 열분해 반응으로 인해 생성물의 선택도가 정확하지 않음을 알려준다.
In this study, hydrocarcking of vacuum residue was carried out in an autoclave reactor at 450°C and 500 °c with a commercial catalyst (HDM) and the quantitative product distributions were analyzed by GC-SIMDIS method or simple distillation. During catalytic hydrocracking, thermal cracking also occurred together with catalytic cracking and the higher conversion and selectivity of gasoline and naphtha were obtained at high reaction temperature. GC-SIMDIS and simple distillation revealed different results for the analysis of products produced at different hydrocracking temperatures; almost same results were obtained for the product produced at 500°C but different ones for the product produced at 450 °c. In the analysis of product produced at 450°C, the GC-SIMDIS showed that a main product was VGO while a main product in the simple distillation was diesel, which implies that the simple distillation for the 450°C reaction was not accurate due to thermal cracking of the product by the simple distillation.
Keywords:Hydrocracking;Simple distillation;GC-SIMDIS;Thermal cracking;Vacuum residue