Binding of Thioether Sulfur to Trivalent Chromium - A Family of Crs2N2O2 Complexes Derived from Acyclic Ligands

Pattanayak S; Das DK; Chakraborty P; Chakravorty A

Inorganic Chemistry, Vol.34, No.26, 6556-6558, 1995

Pattanayak S, Das DK, Chakraborty P, Chakravorty A

The title complexes are of type [Cr(RxL)]ClO4 obtained from dithiaalkyl-substituted triazene 1-oxides [RN(O)NNHC6H4S](2)(CH2)(x) (H(2)RxL; R = Me, Ph; x = 2, 3), chromium(III) chloride tetrahydrate, and sodium perchlorate. We have here the first structurally characterized chromium(III)-thioether binding by an acyclic ligand.

Keywords:INCORPORATING THIOETHER;CRYSTAL-STRUCTURE;OXIDATION-STATES;FROZEN SOLUTIONS;METAL-COMPLEXES;LIGATED NICKEL;COORDINATION;CHEMISTRY;RESONANCE;SPECTRA