To elaborate on superhydrophobic surfaces, we report the electrochemical synthesis, surface morphology, and wettability of hydrocarbon conductive polymer films obtained by the electrodeposition of polythiophene, poly(3.4-ethylenedioxythiophene) (i.e., PEDOT), and poly(3,4-ethylenedioxypyrrole) (i.e., PEDOP) derivatives. Highly hydrophobic films were obtained from n-C14H29 and n-C8H17 chains in the cases of polythiophenes and PEDOP, respectively. By contrast, superhydrophobic films were formed by the deposition of PEDOT substituted with n-C10H21 chains (PEDOT-methyl undecanoate): static contact angle approximate to 160.60 degrees, hysteresis approximate to 2 degrees, and sliding. angle approximate to 30 degrees. Their surface properties were compared to those of previously reported fluorinated analogues. The water-repellent properties of PEDOT-methyl undecanoate were similar to the best surface properties obtained with fluorinated monomers. Even if the main approach for the chemical factor to build up superhydrophobic surfaces is via a coating of a fluorinated compound, this work confirms that the formation of fractal surfaces is able to achieve super-anti-wetting properties within a hydrocarbon series (less expensive with a favorable ecotoxic approach), and it opens a new path to bioinspired surfaces.