Journal of the American Chemical Society, Vol.132, No.6, 1756-1756, 2010
Probing the Magnetic Properties of Three Interconvertible Redox States of a Single-Molecule Magnet with Magnetic Circular Dichroism Spectroscopy
The hysteresis of magnetization of the anionic, neutral, and cationic forms of a bis(phthalocyaninato)terbium-based complex ([Pc2Tb](-/0/+) have been determined Using magnetic circular dichroism (MCD) spectroscopy In frozen dilute solutions at low temperatures (1.5 K) showing that the three oxidation states of the complex exhibit single-molecule magnetic behaviors.