Journal of Supercritical Fluids, Vol.55, No.3, 1023-1026, 2011
Palladocarbosilane dendrons in supercritical carbon dioxide. Catalytic behaviour in the asymmetric hydrovinylation of styrene
The palladocarbosilane dendrons 1 and 2, containing the P-stereogenic phosphine fragment at the focal point are soluble in supercritical CO2 medium and capable to catalyze the asymmetric hydrovinylation of styrene with good activity and enantiomeric excesses. (C) 2010 Elsevier B.V. All rights reserved.