Activated carbons were prepared via a pyrolysis of sucrose followed by activation in the stream of CO2 gas for 2-6 h at 900 degrees C to tune the pore size distribution (PSD) and increase the specific surface area (SSA). The porosity of the activated sucrose derived carbons (ASCs) has been characterized using N-2 sorption measurements. Increasing activation time led to the significant increase in SSA and pore volume of ASCs, among which sucrose derived carbon with 6 h activation time (ASC-6 h) exhibited the highest SSA of 1941 m(2) g(-1) and the highest micropore volume of 0.87 cm(3) g(-1). Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and galvanostatic charge-discharge cycle tests have been applied to investigate the capacitive performance of the ASC electrodes in ionic liquids (ILs) at room and elevated temperatures. The ASC-6 h electrodes in ethyl-dimethyl-propyl-ammonium bis (trifluoromethylsulfonyl) imide (EdMPNTf(2)N) showed specific capacitance in excess of 170 F g(-1) at 60 degrees C, whereas the same electrodes in 1-ethyl-3-methylimidazolium tetrafluoroborate (EMImBF(4)) showed slightly lower capacitance but significantly better rate performance. (C) 2011 Elsevier B.V. All rights reserved.