An analytical, one-dimensional, steady state model is employed to solve for overpotentials at the catalyst layers along with the liquid water and methanol distributions at the anode, and oxygen transport at the cathode. An iterative method is utilized to calculate the cell temperature at each cell current density. A comprehensive exergy analysis considering all possible species inside the cell during normal operation is presented. The contributions of different types of irreversibilities including overpotentials at the anode and cathode, methanol crossover, contract resistance, and proton conductivity of the membrane are investigated. Of all losses. overpotentials is conjunction with the methanol crossover are considered as the major exergy destruction sources inside the cell during the normal operation. While the exergy losses due to electrochemical reactions are more significant at higher current densities, exergy destruction by methanol crossover at the cathode plays more important role at lower currents. It is also found that the first-law efficiency of passive direct methanol fuel cell increases as the methanol solution in the tank increases in concentration from 1M and 3M. However, this is not the case with the second-law efficiency which is always decreasing as the concentration of the methanol solution in the tank increases. (C) 2010 Elsevier B.V. All rights reserved.