화학공학소재연구정보센터
Journal of Power Sources, Vol.195, No.13, 3996-4001, 2010
Direct utilization of methanol and ethanol in solid oxide fuel cells using Cu-Co(Ru)/Zr0.35Ce0.65O2-delta anodes
The direct utilization of methanol (MeOH) and ethanol (EtOH) was investigated on Cu-Co(Ru)/Zr0.35Ce0.65O2 anodes for solid oxide fuel cells (SOFC) prepared by impregnation. Cells had similar performance and stability in H-2 and MeOH, while in EtOH the performance varied with time; that is, the power density initially increased, and then declined exponentially. This behavior was likely a consequence of carbon deposition that initially improved electronic conductivity to the anode functional layer, and subsequently blocked active sites. For all cells, the performance was recovered by re-exposing the anode to humidified hydrogen. In some cases, the cell performance exceeded the initial activity measured in hydrogen. Thus, the direct utilization of MeOH and EtOH did not irreversibly deactivate the Co(Ru)/Zr0.35Ce0.65O2 anodes. (C) 2010 Elsevier B.V. All rights reserved.