A new class of nanocomposite has been fabricated from liquid crystalline (LC) epoxy resin of 4,4'-bis(2,3-epoxypropoxy) biphenyl (BP), 4,4'-diamino-diphenyl sulfone (DDS), and multiwalled carbon nanotubes (CNTs). The surface of the CNTs was functionalized by LC epoxy resin (ef-CNT). The ef-CNT can be blended well with the BP that is further cured with an equivalent of DDS to form nanocomposite. We have studied the curing kinetics of this nanocomposite using isothermal and nonisothermal differential scanning calorimetry (DSC). The dependence of the conversion on time can fit into the autocatalytic model before the vitrification, and then it becomes diffusion control process. The reaction rate increases and the activation energy decreases with increasing concentration of the ef-CNT. At 10 wt % of ef-CNT, the activation energy of nanocomposite curing is lowered by about 20% when compared with the neat BP/DDS resin. If the ef-CNT was replaced by thermal-insulating TiO2 nanorods on the same weight basis, the decrease of activation energy was not observed. The result indicates the accelerating effect on the nanocomposite was raised from the high-thermal conductivity of CNT and aligned LC epoxy resin. However, at ef-CNT concentration higher than 2 wt %, the accelerating effect of ef-CNTs also antedates the vitrification and turns the reaction to diffusion control driven. As the molecular motions are limited, the degree of cure is lowered. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 49: 301-309, 2011