Biobased, unsaturated polyesters derived from isosorbide, maleic anhydride, and succinic acid were synthesized and characterized. The presence of maleic anhydride units in the structure of the polyesters allowed converting them into cured coatings by radical copolymerization with crosslinking agents such as 2-hydroxyethyl methacrylate, N-vinyl-2-pyrrolidinone, acrylic acid or methacrylamide. The investigated polyesters were obtained via bulk polycondensation, catalyzed by titanium(IV) n-butoxide. 2D NMR and MALDI-Tof-MS spectroscopy proved that this polymerization resulted in isomerization of maleic acid units into fumaric ones and in the formation of slightly branched structures by the reaction of isosorbide (end) groups with main chain unsaturated bonds. Moreover, some double bonds proved to have reacted with the condensation by-product water. The resulting polyesters displayed the expected correlation between variables such as molecular weight and content of unsaturated bonds and their T, values. Since the thermal properties of the obtained polyesters were appropriate for coating applications, the polymers were crosslinked with unsaturated monomers by radical copolymerization. The crosslinking process was studied using FTIR spectroscopy and by measurements of the soluble part of the cured coatings. (C) 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2885-2895, 2010