A comparative study of thermal and catalytic degradation of polyethylene wastes has been carried out with the aim of obtaining chemical compounds with potential use in the chemical industry and the energy production. Polyethylene wastes were obtained from polyethylene bags used in supermarkets. Catalysts utilized in the study were silica gel, 5A molecular sieve and activated carbon. The pyrolysis was performed in a batch reactor at 450,500 and 700 degrees C during 2 h for each catalyst. The ratio catalyst/PE was 10% w/w and the solid and gaseous products were analyzed by gas chromatography and mass spectrometry. The optimum operation temperature and the influence of the three catalysts are discussed with regards to the products formed. The best temperature for degradation with silica gel and activated carbon as catalysts was 450 degrees C and with 5A molecular sieve was 700 degrees C. Degradation products of PE (solid fraction and gas fraction) are depending on temperature and catalyst used. External surface and structure of catalysts were visualized by Scanning Electron Microscopy (SEM) and the contribution on product distribution is commented. All products from different degradations could be used as feed stocks in chemical industry or in energy production based on the value of heat of combustion for solid fraction (45 000 J/g), similar to the heat of combustion of commercial fuels. (C) 2011 Elsevier B.V. All rights reserved.