Pd catalyst supported on mesoporous silica-carbon nano-composite (Pd/MSCN) was prepared by the method of wet impregnation, and its activity for hydrodechlorination (HOC) of 2-chlorophenol, 4-chlorophenol and 2,4-dichlorophenol was evaluated at 258-313 K under ordinary hydrogen pressure by using triethylamine (Et3N) as a base additive. XRD analysis indicates that Pd/MSCN catalyst possesses the ordered mesostructure. Meanwhile, the results from TEM and H-2 chemisorption analysis indicate the high dispersion of Pd on MSCN with Pd nanoparticles whose average size is 3.2 nm. For the first time, the high activity of nano-size Pd on MSCN for HDC of chlorophenols was observed at 258 K. In addition, it was found that the inhibition effect of Et3N on HOC existed obviously, and can be efficiently reduced by stepwise addition of Et3N. The correlations of the dielectric constants of base and the polarity of solvent to the activity of Pd/MSCN for HOC of chlorophenols were obtained. (C) 2011 Published by Elsevier B.V.