The by-products of the municipal solid waste incineration (MSWI) generally contain hazardous pollutants, with particular relevance to air pollution control (APC) residues. This waste may be harmful to health and detrimental to the environmental condition, mainly due to soluble salts, toxic heavy metals and trace organic compounds. Solidification/stabilization (S/S) with binders is a common industrial technology for treating such residues, involving however, a significant increase in the final mass that is landfilled. In our work, the chemical stabilization of APC residues by using NaHS center dot xH(2)O, H3PO4, Na2CO3, C5H10NNaS2 center dot H2O, Na2O center dot SiO2 was investigated, and it was possible to conclude that all these additives lead to an improvement of the stabilization process of the most problematic heavy metals. Indeed, compliance leaching tests showed that after the stabilization treatment the waste becomes non-hazardous with respect to heavy metals. Chromium revealed to be a problematic metal, mainly when H-3 PO4, Na2CO3 and Na2O center dot SiO2 were used for stabilization. Nevertheless, soluble phosphates are the most efficient additives for stabilizing the overall metals. The effect of the additives tested on the elements associated with soluble salts (K, Na, Cl-) is almost negligible, and therefore, the soluble fraction is hardly reduced without further treatment, such as pre-washing. (C) 2010 Elsevier B.V. All rights reserved.