in this study, we demonstrate an electro-Fenton (E-Fenton) system constructed with a novel sandwich film cathode (SFC). For the fabrication of SFC, Fe2+-chitosan (Fe-CHI) was first deposited on foam nickel (Fe-CHI/Ni). Then two pieces of Fe-CHI/Ni was used to fasten one piece of activated carbon fiber (ACF) to obtain a Fe-CHI/Ni[ACF]Fe-CHI/Ni sandwich film cathode. We interestingly found that this SFC based E-Fenton system could effectively degrade rodamine B with in situ generating both hydrogen peroxide and iron ions. Its degradation efficiency was significantly higher than those of the E-Fenton systems constructed with composite cathodes of carbon nanotubes with Fe@Fe2O3 core-shell nanowires or Cu2O nanocubes reported in our previous studies. Hydrogen peroxide electrogenerated through the reduction Of O-2 adsorbed on the sandwich film cathode and the iron ions produced by the leakage from Fe2+ chitosan film during the E-Fenton reaction were, respectively, monitored, providing clues to understand the high efficiency of this novel SFC based E-Fenton system. More importantly, this low-cost sandwich film cathode was very stable and could be reused without catalytic activity decrease, suggesting its potential application in the wastewater treatment. (C) 2009 Elsevier B.V. All rights reserved.