화학공학소재연구정보센터
Fluid Phase Equilibria, Vol.298, No.1, 38-47, 2010
Kinetic of hydrate formation of propane and its mixture with methane in a circulating flow reactor
Kinetics of hydrate formation for propane and its mixture with 73% methane have been studied experimentally and theoretically at pressure up to 2 MPa and temperature up to 277.65 K in a 10 m circulating flow reactor. A mathematical model has been developed for the process of hydrate formation based on crystallization, mass transfer and thermodynamics concepts. The amounts of gas consumptions due to hydrate formation are measured experimentally and predicted by the model. The agreement between the experimental measured gas consumptions and predicted values by the mathematical model are very good and the average deviation errors in the prediction of gas consumption are less than 10%. (C) 2010 Elsevier B.V. All rights reserved.