Two-phase aqueous systems of cetyltrimethylammonium bromide/sodium dodecyl sulfate with and without polyethylene glycol

Fei Wang; Ting Chen; Yazhuo Shang; Honglai Liu

Korean Journal of Chemical Engineering, Vol.28, No.3, 923-926, March, 2011

DOI10.1007/s11814-010-0456-4 Export Citation

Two-phase aqueous systems of cetyltrimethylammonium bromide/sodium dodecyl sulfate with and without polyethylene glycol

Fei Wang, Ting Chen, Yazhuo Shang^†, and Honglai Liu

Key Laboratory for Advanced Materials, East China University of Science and Technology, Shanghai 200237, China

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Aqueous two-phase systems of cetyltrimethylammonium bromide and sodium dodecyl sulfate mixtures without and with polyethylene glycol (PEG) added have been studied at 313.15 K. The results have shown that PEG has a strong effect on the phase diagram of ATPS and microstructures of surfactants aggregates. The addition of PEG leads to the formation of bigger surfactant aggregates, which can be attributed to both the screening effect and the connection effect of PEG. All ATPS, especially those with PEG added, may have potential applications in separation and purification of biomaterials.

Keywords:Aqueous Two-phase System;CTAB;SDS;Polyethylene Glycol

[References]

Albertsson PA, Partition of cell particles and macromolecules, 3rd edition, Wiley, New York (1986)
Hustedt H, Kroner KH, Kula MR, Trend in Biotechnology., 3, 139 (1985)
Tjerneld F, Berner S, Cajarville A, Johansson G, Enzym. Microb. Technol., 8, 417 (1986)
Buckmann AF, Michael M, Kula MR, Biotechnol. Appl. Biochem., 9, 258 (1987)
Tjerneld F, Johansson G, Joelsson M, Biotechnol. Bioeng., 30, 809 (1987)
Walter H, Johanson G, Brooks DE, Anal. Biochem., 197, 1 (1991)
Nikas YJ, Liu CL, Srivastava T, Abbott NL, Blankschtein D, Macromolecules., 25, 4797 (1992)
Yu ZJ, Zhao GX, J. Colloid Interf. Sci., 130, 421 (1989)
Shang YZ, Liu HL, Hu Y, Prausnitz JM, J. Disp. Sci. Technol., 27, 335 (2006)
Nan YQ, Liu HL, Hu Y, J. Disp. Sci. Technol., 28, 255 (2007)
Liu L, Rosen MJ, J. Colloid Interface Sci., 179(2), 454 (1996)
Yatcilla MT, Herrington KL, Brasher LL, Kaler EW, Chiruvolu S, Zasadzinski JA, J. Phys. Chem., 100(14), 5874 (1996)
Xiao JX, Sivars U, Tjerneld F, J. Chromatogr. B., 743, 327 (2000)
Shang YZ, Liu HL, Hu Y, Prausnitz JM, Colloids and Surfaces A: Physicochem. Eng. Aspects., 302, 58 (2007)
Lucassen REH, Lucassen J, Giles D, J. Colloid Interf. Sci., 81, 150 (1981)
Kaler EW, Herrington KL, Murthy AK, J. Phys. Chem., 96, 6698 (1992)
Liu CL, Nikas YJ, Blankschtein D, Biotechnol. Bioeng., 52(2), 185 (1996)
Yu ZJ, Zhao GX, J. Colloid Interf. Sci., 421, 130 (1989)
Nan YQ, Liu HL, Hu Y, Colloids and Surfaces A: Physcochem. Eng. Aspects., 269, 101 (2005)
Teng HN, PhD thesis, East China University of Science and Technology, 13 (2001)

[Referenced By]

[1] Albertsson PA, Partition of cell particles and macromolecules, 3rd edition, Wiley, New York (1986)

[2] Hustedt H, Kroner KH, Kula MR, Trend in Biotechnology., 3, 139 (1985)

[3] Tjerneld F, Berner S, Cajarville A, Johansson G, Enzym. Microb. Technol., 8, 417 (1986)

[4] Buckmann AF, Michael M, Kula MR, Biotechnol. Appl. Biochem., 9, 258 (1987)

[5] Tjerneld F, Johansson G, Joelsson M, Biotechnol. Bioeng., 30, 809 (1987)

[6] Walter H, Johanson G, Brooks DE, Anal. Biochem., 197, 1 (1991)

[7] Nikas YJ, Liu CL, Srivastava T, Abbott NL, Blankschtein D, Macromolecules., 25, 4797 (1992)

[8] Yu ZJ, Zhao GX, J. Colloid Interf. Sci., 130, 421 (1989)

[9] Shang YZ, Liu HL, Hu Y, Prausnitz JM, J. Disp. Sci. Technol., 27, 335 (2006)

[10] Nan YQ, Liu HL, Hu Y, J. Disp. Sci. Technol., 28, 255 (2007)

[11] Liu L, Rosen MJ, J. Colloid Interface Sci., 179(2), 454 (1996)

[12] Yatcilla MT, Herrington KL, Brasher LL, Kaler EW, Chiruvolu S, Zasadzinski JA, J. Phys. Chem., 100(14), 5874 (1996)

[13] Xiao JX, Sivars U, Tjerneld F, J. Chromatogr. B., 743, 327 (2000)

[14] Shang YZ, Liu HL, Hu Y, Prausnitz JM, Colloids and Surfaces A: Physicochem. Eng. Aspects., 302, 58 (2007)

[15] Lucassen REH, Lucassen J, Giles D, J. Colloid Interf. Sci., 81, 150 (1981)

[16] Kaler EW, Herrington KL, Murthy AK, J. Phys. Chem., 96, 6698 (1992)

[17] Liu CL, Nikas YJ, Blankschtein D, Biotechnol. Bioeng., 52(2), 185 (1996)

[18] Yu ZJ, Zhao GX, J. Colloid Interf. Sci., 421, 130 (1989)

[19] Nan YQ, Liu HL, Hu Y, Colloids and Surfaces A: Physcochem. Eng. Aspects., 269, 101 (2005)

[20] Teng HN, PhD thesis, East China University of Science and Technology, 13 (2001)