화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.28, No.2, 497-501, February, 2011
Copyrolysis of block polypropylene with waste wood chip
E-mail:
In this study, the copyrolysis of waste wood chip (WC) and block polypropylene (PP) was studied to investigate how the characteristics of bio-oils are affected by copyrolysis. The thermogravimetric analysis performed with a temperature rise of 20 ℃/min, from room temperature to 600 ℃, showed that the decomposition temperature of PP was a little higher via copyrolysis than the single-component pyrolysis. This result suggests that the characteristics of the pyrolysis of PP were affected by the pyrolysis products of WC. The Py-GC/MS analysis of the copyrolysis products detected some new compounds that had not been detected in the single-component pyrolysis products, indicating interactions between the products of WC and PP pyrolyses. The results of the experiments using a fixed bed reactor showed improved properties of the bio-oil obtained from the copyrolysis compared to those of the bio-oil obtained from the single-component pyrolysis: increased carbon and hydrogen contents, decreased water content and a significantly increased heating value.
  1. Othman MR, Park YH, Ngo TA, Kim SS, Kim J, Lee KS, Korean J. Chem. Eng., 27(1), 163 (2010)
  2. Kim SS, Agblevor FA, Lim JT, J. Ind. Eng. Chem., 15(2), 247 (2009)
  3. Park HJ, Dong JI, Jeon JK, Park YK, Yoo KS, Kim SS, Kim J, Kim S, Chem. Eng. J., 143(1-3), 124 (2008)
  4. Park HJ, Park YK, Dong JI, Kim JS, Jeon JK, Kim SS, Kim J, Song B, Park J, Lee KJ, Fuel Process. Technol., 90(2), 186 (2009)
  5. Heo HS, Park HJ, Park YK, Ryu C, Suh DJ, Suh YW, Yim JH, Kim SS, Bioresour. Tehcnol., 101, S91 (2010)
  6. Park HJ, Heo HS, Park YK, Yim JH, Jeon JK, Park J, Ryu C, Kim SS, Bioresour. Technol., 101, S83 (2010)
  7. Heo HS, Park HJ, Yim JH, Sohn JM, Park J, Kim SS, Ryu C, Park YK, Bioresour. Technol., 101, 3672 (2010)
  8. Heo HS, Park HJ, Park SH, Kim S, Suh DJ, Suh YW, Kim SS, Park YK, J. Ind. Eng. Chem., 25, 27 (2010)
  9. Park HJ, Heo HS, Yim JH, Jeon JK, Ko YS, Kim SS, Park YK, Korean J. Chem. Eng., 27(1), 73 (2010)
  10. Park HJ, Dong JI, Jeon JK, Yoo KS, Yim JS, Sohn JM, Park YK, J. Ind. Eng. Chem., 13(2), 182 (2007)
  11. Park KH, Park HJ, Kim J, Ryoo R, Jeon JK, Park J, Park YK, J. Nanosci. Nanotechnol., 10, 355 (2010)
  12. Choi HS, Choi YS, Park HC, Korean J. Chem. Eng., 27(4), 1164 (2010)
  13. Park HJ, Heo HS, Jeon JK, Kim J, Ryoo R, Jeong KE, Park YK, Appl. Catal. B: Environ., 95(3-4), 365 (2010)
  14. Lee SH, Heo HS, Jeong KE, Yim JH, Jeon JK, Jung KY, Ko YS, Kim SS, Park YK, J. Nanosci. Nanotechnol., 11, 759 (2011)
  15. Aboulkas A, El Harfi K, El Bouadili A, Energy Conv. Manag., 49(12), 3666 (2008)
  16. Jakab E, Varhegyi G, Faix O, J. Anal. Appl. Pyrol., 56, 273 (2000)
  17. Fraga A, Ruseckaite RA, Jimenez A, Polymer Testing., 24, 526 (2005)
  18. Dong C, Yang Y, Jin B, Horio M, Waste Manage., 27, 1557 (2007)
  19. Marin N, Collura S, Sharypov VI, Beregovtsova NG, Baryshnikov SV, Kuznetsov BN, Cebolla V, Weber JV, J. Anal. Appl. Pyrol., 65, 41 (2002)
  20. Sharypov VI, Beregovtsova NG, Kuznetsov BN, Membrado L, Cebolla VL, Marin N, Weber JV, J. Anal. Appl. Pyrol., 67, 325 (2003)
  21. Cornelissen T, Yperman J, Reggers G, Schreurs S, Carleer R, Fuel., 87, 1031 (2008)
  22. Heo HS, Kim SG, Jeong KE, Jeon JK, Park SH, Kim JM, Kim SS, Park YK, Bioresour. Technol., DOI:10.1016/j.biortech.2010.11.099 (2010)