A new method, pressurized CEC with end-column amperometric detection using carbon paste electrode, has been developed for the separation and determination of five phenolic xenoestiogens in chicken eggs and milk powder samples. Efficient separation of five analytes was performed by pressurized CEC using a mobile phase consisting of 60% v/v ACN and 40% v/v Tris buffer (5 mmol/L, pH 80), +6 kV of applied voltage and 7 0 MPa of supplementary pressure Detection limits of 50, 5, 2, 10 and 20 ng/mL for pentachlorophenol, bisphenol-A, 2,4-dichlorophenol, 4-tert-octylphenol and 4-nonylphenol, respectively, were achieved using carbon paste electrode as working electrode and +0 8 V as detection potential Matrix solid phase dispersion extraction method had been employed during sample preparation procedure, and mean recoveries ranged from 79 2 to 102.6% at different concentrations of phenolic xenoestrogens for spiked egg and milk powder samples were obtained.