화학공학소재연구정보센터
Electrochimica Acta, Vol.54, No.27, 7056-7065, 2009
On the decay of the Lorentz-force-driven convection in vertical concentration stratification during magnetoelectrolysis
We study the temporal development of the Lorentz-force-driven convection in an inhomogeneous magnetic field during copper electrolysis between two vertical electrodes. Using a combination of interferometry and particle image velocimetry we show that the Lorentz-force-driven convection is canceled out even after a moderate duration of the electrolysis. By reversing the current, a re-excitation of the convection is possible which is, however, restricted to a time window of some seconds. The reasons for the decay and re-appearance of the MHD flow are discussed and explained by scaling analysis. (C) 2009 Elsevier Ltd. All rights reserved.