반응성 염료(Reactive Red 218)의 염석결정화계에서의 결정화 속도

한현각; 강혜진; 이종훈; Hyun-Kak Han; Hye-jin kang; Jong-hoon Lee

Korean Chemical Engineering Research, Vol.48, No.6, 712-716, December, 2010

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반응성 염료(Reactive Red 218)의 염석결정화계에서의 결정화 속도

Crystallization Kinetics of Reactive Dye(Reactive Red 218) in Salting-out Crystallization System

한현각^†, 강혜진, 이종훈

순천향대학교 나노화학공학과, 336-745 충남 아산시 신창면 읍내리 646

Hyun-Kak Han^†, Hye-jin kang, and Jong-hoon Lee

Department of chemical Engineering, Soonchunhyang University, 646, Eupnae-ri, Shinchang-myeon, Asan-si, Chungnam 336-745, Korea

E-mail:

초록

염석결정화란 제 3의 성분을 가하여 혼합용매로 만들어 용질의 용해도를 저하시키는 방법으로 염료 용액으로부터 염료 결정화에 염석결정화를 이용하였다. 이번 연구에서 반응성 염료(Reactive Red 218)의 용해도와 결정화 속도를 연구하였다. 그 결과 염료 용액의 용해도는 KCl 농도가 높을수록 용해도가 낮아지는 것을 확인할 수 있었다. 또한 연속식 결정화기에서 반응성 염료(Reactive Red 218)에 대한 결정화 속도식은 결정 성장 속도 G=6.864×10^(-5)△C^(1.207)와 핵 생성속도 B°=4.8×10^(22)△C [1.1×10^(-13)+(ΔC)0.7M(T)2]의 실험식으로 표현할 수 있다.

Salting-out technique was adopted to crystallize dye crystals from dye solution. Solubility of dye solution and crystallization kinetics of Reactive Red 218 was investigated. Solubility of dye solution is decreased by higher KCl concentration. The empirical expressions of salting-out crystallization kinetics for Reactive Red 218 in continuous MSMPR crystallizer was G=6.864×10^(-5)△C^(1.207) and B°=4.8×10^(22)△C [1.1×10^(-13)+(ΔC)0.7M(T)2]

Keywords:Crystallization;Growth Rate;Reactive Dye

[References]

Randolph AD, Larson MA, Theory of Particulate Processes 2nd ed., Academic Press, New York (1988)
Nyvlt J, Industrial Crystallization from Solution Butterworth & Co. Ltd., London (1971)
Mullin JW, Crystallization 3rd ed., Butterworth-Heinemann, London (1993)
PamPlin BR, Crystal Growth 2nd ed., Pergamon Press, London (1980)
Tavare NS, Industrial Crystallization Process Simulation Analysis and Design Plenum Press New York and London (1995)
Mersmann A, Crystallization Technology Handbook Marcel Dekker, Inc. New York-Basel-Hong Kong (1995)
Chen MR, Larson MA, Chem. Eng. Science, 40, 1287 (1985)
Juzaszek P, Larson MA, AIChE J., 23, 460 (1977)
Han HK, Lee SI, Lee CS, Korean J. Chem. Eng., 28, 58 (1989)
Kim HD, Park HS, Shin YJ, Lee CS, Korean J. Chem. Eng., 23, 145 (1985)
Shin YJ, Yun CH, Lee CS, Int. Chem. Eng., 26, 348 (1986)
Jones AG, Mullin JW, Chem. Eng. Sci., 29, 105 (1974)
Mullin JW, Nyvlt J, Chem. Eng. Sci., 26, 369 (1971)
Garside J, Gaska C, Mullin JW, J. Cryst. Growth, 13-14, 510 (1972)
Nyvlt J, The Kinetics of Industrial Crystallization. Elsevier, Amsterdam-Oxford-NewYork-Tokyo (1985)
Han HK, Jung HK, Korean J. Chem. Eng., 26(1), 246 (2009)
Jung HK, Han HK, Kwun CS, Kang HJ, Theor. Appl. Chem. Eng., 14, 426 (2008)
Jung HK, Han HK, Kwun CS, Kang HJ, Theor. Appl. Chem. Eng., 14, 2632 (2008)
Pyun YR, Han HK, Jung HK, Kim BM, Theor. Appl. Chem. Eng., 13, 1620 (2007)
Han HK, Jeong OH, Lim MH, Kim JA, Theor. Appl. Chem. Eng., 11, 329 (2005)
Kim JA, Han HK, Kim BM, Pyun YR, Theor. Appl. Chem. Eng., 12, 1580 (2006)
Kim BM, Han HK, Jung HK, Pyun YR, Theor. Appl. Chem. Eng., 13, 1376 (2007)
Kwon CS, Jung HK, Kang HJ, Han HK, Theor. Appl. Chem. Eng., 14, 286 (2008)

[1] Randolph AD, Larson MA, Theory of Particulate Processes 2nd ed., Academic Press, New York (1988)

[2] Nyvlt J, Industrial Crystallization from Solution Butterworth & Co. Ltd., London (1971)

[3] Mullin JW, Crystallization 3rd ed., Butterworth-Heinemann, London (1993)

[4] PamPlin BR, Crystal Growth 2nd ed., Pergamon Press, London (1980)

[5] Tavare NS, Industrial Crystallization Process Simulation Analysis and Design Plenum Press New York and London (1995)

[6] Mersmann A, Crystallization Technology Handbook Marcel Dekker, Inc. New York-Basel-Hong Kong (1995)

[7] Chen MR, Larson MA, Chem. Eng. Science, 40, 1287 (1985)

[8] Juzaszek P, Larson MA, AIChE J., 23, 460 (1977)

[9] Han HK, Lee SI, Lee CS, Korean J. Chem. Eng., 28, 58 (1989)

[10] Kim HD, Park HS, Shin YJ, Lee CS, Korean J. Chem. Eng., 23, 145 (1985)

[11] Shin YJ, Yun CH, Lee CS, Int. Chem. Eng., 26, 348 (1986)

[12] Jones AG, Mullin JW, Chem. Eng. Sci., 29, 105 (1974)

[13] Mullin JW, Nyvlt J, Chem. Eng. Sci., 26, 369 (1971)

[14] Garside J, Gaska C, Mullin JW, J. Cryst. Growth, 13-14, 510 (1972)

[15] Nyvlt J, The Kinetics of Industrial Crystallization. Elsevier, Amsterdam-Oxford-NewYork-Tokyo (1985)

[16] Han HK, Jung HK, Korean J. Chem. Eng., 26(1), 246 (2009)

[17] Jung HK, Han HK, Kwun CS, Kang HJ, Theor. Appl. Chem. Eng., 14, 426 (2008)

[18] Jung HK, Han HK, Kwun CS, Kang HJ, Theor. Appl. Chem. Eng., 14, 2632 (2008)

[19] Pyun YR, Han HK, Jung HK, Kim BM, Theor. Appl. Chem. Eng., 13, 1620 (2007)

[20] Han HK, Jeong OH, Lim MH, Kim JA, Theor. Appl. Chem. Eng., 11, 329 (2005)

[21] Kim JA, Han HK, Kim BM, Pyun YR, Theor. Appl. Chem. Eng., 12, 1580 (2006)

[22] Kim BM, Han HK, Jung HK, Pyun YR, Theor. Appl. Chem. Eng., 13, 1376 (2007)

[23] Kwon CS, Jung HK, Kang HJ, Han HK, Theor. Appl. Chem. Eng., 14, 286 (2008)