화학공학소재연구정보센터
Chemical Physics Letters, Vol.493, No.1-3, 118-120, 2010
Molecular dynamics simulation of silver nanoparticles in a europium doped sodosilicate glass
Molecular dynamics simulation is applied to an europium doped sodosilicate glass containing silver [(Na-Ag)(2)O-SiO2-Eu2O3]. The silver is implanted in substitution of Na, simulating an ionic exchange. For ionic interactions a modified Born-Mayer-Huggins potential was employed. For the Ag-Ag interaction, a Lennard-Jones (LJ) potential is applied, while for the Eu-Ag interaction, a modified LJ potential is introduced. The particle size increases with the annealing treatment and follows a lognormal law. After 75 ps the average particle size reaches 5.8 atoms (4.8 for Ag and 1.0 for Eu), and it is found that the europium is preferentially situated on these nanoclusters. (C) 2010 Elsevier B.V. All rights reserved.