An LaFe0.5Mg0.5O3/Al2O3/FeCrAl metallic monolith catalyst for the exothermic catalytic combustion of methane and an Ni/SBA-15/Al2O3/FeCrAl metallic monolith catalyst for the endothermic reforming of methane with CO2 have been prepared. A laboratory-scale tubular jacket reactor with the Ni/SBA-15/Al2O3/FeCrAl catalyst packed into its outer jacket and the LaFe0.5Mg0.5O3/Al2O3/FeCrAl catalyst packed into its inner tube was devised and constructed. The reactor allows a coupling of the exothermic and endothermic reactions by virtue of their thermal matching. An experimental study in which the temperature difference between the chamber of the external electric furnace and the metallic monolith catalyst bed in the jacket was kept very small, by adjusting the power supply to the furnace, confirmed that the heat absorbed in the reforming reaction does indeed partly come from that evolved in the catalytic combustion of methane, and that the direct thermal coupling of the two reactions in the reactor can be realized in practice. When the temperature of the electric furnace chamber was 1088 K, and the gas hourly space velocities (GHSVs) of the reactant mixtures passed through the inner tube and the jacket were 382 h(-1) and 40 h(-1), respectively, the conversions of methane and CO2 in the reforming reaction were 93.6% and 91.7%, respectively, and the heat efficiency reached 81.9%. Stability tests showed that neither catalyst underwent deactivation during 150 h on stream. (C) 2009 Elsevier B.V. All rights reserved.