Steam reforming of tar during biomass pyrolysis for hydrogen will not only avoid frequent equipment shutdown for maintenance and repair but also increase hydrogen yield. In this paper, the effects of temperature and steam/carbon molar ration on steam reforming of toluene as model compound of tar was studied by simulation of thermodynamic equilibrium and experiments using Ni/cordierite catalyst in a fixed bed reactor. The results of thermodynamic simulations indicate that the S/C molar ratio of 2 and the temperature range from 1023 K to 1173 K provide favorable operating conditions for steam reforming of toluene in order to get high hydrogen productivity. These operating parameters were adopted in the experiments using Ni/cordierite catalyst in a fixed bed reactor. H-2 content remains about 66 mol I and slightly varies with the increasing temperature. Conversion efficiency of toluene increases with temperature, reaching 94.1% at 1173 K. The simulation was improved in order to be closer to experimental results. It is found that only a very small amount of toluene did not participate in the reaction. In the aromatic hydrocarbons of reactive system, benzene and naphthalene were the main products and the proportion of naphthalene decreases with increasing temperature while that of benzene increases. (C) 2009 Elsevier Ltd. All rights reserved.