황산 표면개질 메조다공 실리카를 이용한 푸르푸랄 제조에 관한 연구

김은규; 김샛별; 박은덕; 김상욱; Eun Gyu Kim; Saet Byul Kim; Eun Duck Park; Sang Wook Kim

Clean Technology, Vol.16, No.2, 95-102, June, 2010

Export Citation

황산 표면개질 메조다공 실리카를 이용한 푸르푸랄 제조에 관한 연구

Dehydration of D-Xylose into Furfural Using Propylsulfonic Acid Modified Mesoporous Silica

김은규, 김샛별¹, 박은덕 ¹, 김상욱^†

아주대학교 분자과학기술학과, 경기도 수원시 영통구 원천동 산 5번지
¹아주대학교 에너지시스템학부, 경기도 수원시 영통구 원천동 산 5번지

Eun Gyu Kim, Saet Byul Kim¹, Eun Duck Park¹, and Sang Wook Kim^†

Department of Molecular Science and Technology, Ajou University, San 5 Woncheon-dong, Yeongtong-gu, Suwon 443-749, Korea
¹Division of Energy Systems Research, and Division of Chemical Engineering andMaterials Engineering, Ajou University, San 5 Woncheon-dong, Yeongtong-gu, Suwon 443-749, Korea

E-mail:

초록

MCM 41, HMS, SBA 15와 같은 메조다공 실리카에 post-synthesis와 co-condensation 방법으로 황산이 결합된 촉매를 제조하였다. 이 메조다공 실리카들을 자일로즈 탈수화반응의 촉매로 사용하여 푸르푸랄을 합성하였으며 관련된 반응특성을 연구하였다. 그 결과, 친환경적 용매인 물을 사용한 경우에도 양호한 전환율과 선택도를 얻을 수 있었다. 아울러 실리카 표면에 황산의 양이 증가할수록 자일로즈의 전환율이 증가하는 것을 알 수 있었고, 동일한 반응 조건에서 다른 고체산 촉매인 제올라이트와 감마알루미나를 사용했을 때 보다 양호한 선택도 결과를 얻었다.

Sulfonic acid (-SO3H) functionalized mesoporous silica containing HMS, SBA 15(S15), MCM 41(M41) were synthesized by post-synthesis and co-condensation method. Their catalytic performance is tested by dehydration reaction of D-xylose to furfural. As a result, good conversion and selectivity was obtained using water as an environmentally friendly solvent. Additionally, increased amounts of sulfuric acid in catalysts resulted in improved conversion of D-xylose. All of the acid-functionalized mesoporous silica showed higher selectivity than other solid acids such as γ-AI2O3 and zeolite.

Keywords:메조포러스 실리카;푸르푸랄;탈수화반응;고체산;Mesoporous silica;Furfural;Dehydration;Solid acid

[References]

http://wl.I-W.furan.com/firrt.UraUnduslriaCchemicatintemlediate. html
Zeitsch KJ, "The Chemistry and Technology of Furfiual and Its Many By-Products, first ed., in: Sugar Series," Elsevier, The Netherlands, 13 (2000)
Ahmad T, Kenne L, Olsson K, Theander O, Carbohyd Res., 276(2), 309 (1995)
Antal Jr, MJ, Leesomboon T, Mok WS, Rochards GN, Carbohydrate Res., 217(1), 71 (1991)
Moreaua C, Belgacemb MN, Gandinib A, Top. Calal., 27(1-4), 11 (2004)
Dias AS, Pillinger M, Valente AA, J. Catal., 229(2), 414 (2005)
Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am Chem. Soc., 114(2), 10834 (1992)
Bossaert WD, De Vos DE, Van Rhijn WM, Bullen J, Grobet PJ, Jacobs PA, J. Catal., 182(1), 156 (1999)
Saravanamurugan S, Sujandi, Prasetyanto EA, Park SE, Micropor. Mesopor. Mat., 112(113), 97 (2008)
Schulz-Ekloff G, Rathousky J, Zukal A, Micropor. Mesopor·. Mat., 27(2-3), 273 (1999)
Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)
Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)
Margolese D, Melero JA, Christiansen SC, Chmelka BF, Stucky GD, Chern. Mater., 12(8), 2448 (2000)
Mori Y, Pinnavaia TJ, Chern. Mater., 13(8), 2173 (2001)
Benesi HA, J. Am Chern. Soc., 78(21), 5490 (1956)
Schneider P, Appl. Catal. A: Gen., 129(2), 157 (1995)
O'Neill R, Ahmad MN, Vanoye L, Aiouache F, Ind. Eng. Chem. Res., 48(9), 4300 (2009)

[Related Articles]

[1] http://wl.I-W.furan.com/firrt.UraUnduslriaCchemicatintemlediate. html

[2] Zeitsch KJ, "The Chemistry and Technology of Furfiual and Its Many By-Products, first ed., in: Sugar Series," Elsevier, The Netherlands, 13 (2000)

[3] Ahmad T, Kenne L, Olsson K, Theander O, Carbohyd Res., 276(2), 309 (1995)

[4] Antal Jr, MJ, Leesomboon T, Mok WS, Rochards GN, Carbohydrate Res., 217(1), 71 (1991)

[5] Moreaua C, Belgacemb MN, Gandinib A, Top. Calal., 27(1-4), 11 (2004)

[6] Dias AS, Pillinger M, Valente AA, J. Catal., 229(2), 414 (2005)

[7] Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schmitt KD, Chu CTW, Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL, J. Am Chem. Soc., 114(2), 10834 (1992)

[8] Bossaert WD, De Vos DE, Van Rhijn WM, Bullen J, Grobet PJ, Jacobs PA, J. Catal., 182(1), 156 (1999)

[9] Saravanamurugan S, Sujandi, Prasetyanto EA, Park SE, Micropor. Mesopor. Mat., 112(113), 97 (2008)

[10] Schulz-Ekloff G, Rathousky J, Zukal A, Micropor. Mesopor·. Mat., 27(2-3), 273 (1999)

[11] Zhao DY, Feng JL, Huo QS, Melosh N, Fredrickson GH, Chmelka BF, Stucky GD, Science, 279(5350), 548 (1998)

[12] Tanev PT, Pinnavaia TJ, Science, 267(5199), 865 (1995)

[13] Margolese D, Melero JA, Christiansen SC, Chmelka BF, Stucky GD, Chern. Mater., 12(8), 2448 (2000)

[14] Mori Y, Pinnavaia TJ, Chern. Mater., 13(8), 2173 (2001)

[15] Benesi HA, J. Am Chern. Soc., 78(21), 5490 (1956)

[16] Schneider P, Appl. Catal. A: Gen., 129(2), 157 (1995)

[17] O'Neill R, Ahmad MN, Vanoye L, Aiouache F, Ind. Eng. Chem. Res., 48(9), 4300 (2009)