EFFECT OF PHASE TRANSFER CATALYST ON CO SUBSTITUTION OF Mo(CO)<SUB>6</SUB>

Yang HS; Park HS; Kim YH

Korean Journal of Chemical Engineering, Vol.9, No.1, 23-28, January, 1992

EFFECT OF PHASE TRANSFER CATALYST ON CO SUBSTITUTION OF Mo(CO)₆

The effect of Q⁺OH^-was studied, which is formed in NaOH solution used for anion exchange with PTC, on CO substitution of molybdenum hexacarbonyl complex by strong electron donating ligand, 2,2-bipyridine. The change of product yield was discussed according to the amount and types of solvent and PTC, Their compositions, reaction temperature and time, and different cation and anion of PTC.

[References]

Starks CM, Liotta C, "Phase Transfer Catalyst," Academic Press (1987)
Abbayes H, Alper H, J. Am. Chem. Soc., 99, 98 (1977)
Manuta DM, Lees AJ, J. Chem., 64, 637 (1987)
Lewis KE, Golden DM, Smith GP, J. Am. Chem. Soc., 106, 3905 (1984)
Collman JP, Hegedus LS, Norton JR, Finke RG, "Principles and Applications of Organotransition Metal Chemistry," Mill Valley, California (1987)
Chatt J, Leigh CJ, Thankarajan N, J. Org. Chem., 29, 105 (1971)
Alber MO, Singleton E, J. Chem., 63, 444 (1986)
Hui KY, Shaw BL, J. Org. Chem., 124, 262 (1977)
Darensbourg DJ, Bellus PA, Froelich JA, J. Am. Chem. Soc., 102, 4688 (1980)
Stiddard MHB, J. Chem. Soc., 756 (1963)
Manuta DM, Lees AJ, J. Chem., 7 (1987)
Kolthammer BWS, Legzdins P, Malito JT, Inorg. Synth., 19, 208 (1979)
Stiddard MHB, J. Chem. Soc., 4712 (1962)

[Referenced By]

[1] Starks CM, Liotta C, "Phase Transfer Catalyst," Academic Press (1987)

[2] Abbayes H, Alper H, J. Am. Chem. Soc., 99, 98 (1977)

[3] Manuta DM, Lees AJ, J. Chem., 64, 637 (1987)

[4] Lewis KE, Golden DM, Smith GP, J. Am. Chem. Soc., 106, 3905 (1984)

[5] Collman JP, Hegedus LS, Norton JR, Finke RG, "Principles and Applications of Organotransition Metal Chemistry," Mill Valley, California (1987)

[6] Chatt J, Leigh CJ, Thankarajan N, J. Org. Chem., 29, 105 (1971)

[7] Alber MO, Singleton E, J. Chem., 63, 444 (1986)

[8] Hui KY, Shaw BL, J. Org. Chem., 124, 262 (1977)

[9] Darensbourg DJ, Bellus PA, Froelich JA, J. Am. Chem. Soc., 102, 4688 (1980)

[10] Stiddard MHB, J. Chem. Soc., 756 (1963)

[11] Manuta DM, Lees AJ, J. Chem., 7 (1987)

[12] Kolthammer BWS, Legzdins P, Malito JT, Inorg. Synth., 19, 208 (1979)

[13] Stiddard MHB, J. Chem. Soc., 4712 (1962)