SOLUBILITIES OF MIXED STRONG 1:1 ELECTROLYTES IN WATER AND WATER-METHANOL MIXTURES

Shim YS; Lee CS

Korean Journal of Chemical Engineering, Vol.8, No.4, 227-234, October, 1991

A model[1] recently proposed for mixed electrolytes-mixed solvent systems was tested for activity coefficients of electrolytes, the transfer gibbs free energy and the solubilities of electrolytes. The model is comprised of the Delbye-Huckel term, the born term and the NRTL term similar to Cruz and Renon’s, but has several simplifying features. The model was found applicable to mixed electrolyte-aqueous systems without any interaction parameter between electrolytes. But since the available data are limited, the test for applicability to mixed solvent systems needs further studies.

[References]

Kim HD, Lee CS, HWAHAK KONGHAK, 27(4), 548 (1989)
Han GS, Jung WK, Lee CS, HWAHAK KONGHAK, 27(5), 657 (1989)
Cruz J, Renon H, AIChE J., 24, 817 (1978)
Harned HS, Owen BB, "Physical Chemistry of Electrolyte Solutions," Reinhold, New York (1950)
Burgess J, "Metal Ions in Solution," John Wiley & Sons, N.Y. (1978)
Albright PS, Gosting LJ, J. Am. Chem. Soc., 68, 1061 (1946)
Feakins D, Voice PJ, J. Chem. Soc.-Faraday Trans., 68, 1390 (1972)
Malahlas L, Popovych O, J. Chem. Eng. Data, 27, 105 (1982)
Rastogi A, Tassios D, Ind. Eng. Chem. Res., 26, 1344 (1987)
Pitzer KS, Kim JJ, J. Am. Chem. Soc., 96, 5701 (1974)
Harned HS, Ehlers RW, J. Am. Chem. Soc., 38, 70 (1942)
Robinson RA, Trans. Faraday Soc., 41, 756 (1945)
Robinson RA, Trans. Roy. Soc. N.Z., 75, 203 (1945)
Robinson RA, Trans. Faraday Soc., 35, 1217 (1939)
Robinson RA, J. Phys. Chem., 65, 662 (1961)
Lanier RD, J. Phys. Chem., 69, 2697 (1965)
Malahlas L, Popovych O, J. Chem. Eng. Data, 27, 105 (1982)
Shim YS, Kim HD, Lee CS, HWAHAK KONGHAK, 29, 630 (1991)

[Referenced By]

[1] Kim HD, Lee CS, HWAHAK KONGHAK, 27(4), 548 (1989)

[2] Han GS, Jung WK, Lee CS, HWAHAK KONGHAK, 27(5), 657 (1989)

[3] Cruz J, Renon H, AIChE J., 24, 817 (1978)

[4] Harned HS, Owen BB, "Physical Chemistry of Electrolyte Solutions," Reinhold, New York (1950)

[5] Burgess J, "Metal Ions in Solution," John Wiley & Sons, N.Y. (1978)

[6] Albright PS, Gosting LJ, J. Am. Chem. Soc., 68, 1061 (1946)

[7] Feakins D, Voice PJ, J. Chem. Soc.-Faraday Trans., 68, 1390 (1972)

[8] Malahlas L, Popovych O, J. Chem. Eng. Data, 27, 105 (1982)

[9] Rastogi A, Tassios D, Ind. Eng. Chem. Res., 26, 1344 (1987)

[10] Pitzer KS, Kim JJ, J. Am. Chem. Soc., 96, 5701 (1974)

[11] Harned HS, Ehlers RW, J. Am. Chem. Soc., 38, 70 (1942)

[12] Robinson RA, Trans. Faraday Soc., 41, 756 (1945)

[13] Robinson RA, Trans. Roy. Soc. N.Z., 75, 203 (1945)

[14] Robinson RA, Trans. Faraday Soc., 35, 1217 (1939)

[15] Robinson RA, J. Phys. Chem., 65, 662 (1961)

[16] Lanier RD, J. Phys. Chem., 69, 2697 (1965)

[17] Malahlas L, Popovych O, J. Chem. Eng. Data, 27, 105 (1982)

[18] Shim YS, Kim HD, Lee CS, HWAHAK KONGHAK, 29, 630 (1991)