WOx/SBA-15 nanocomposite materials with different WOx loadings were prepared by one step hydrothermal synthesis and used in the vapor-phase Beckmann rearrangement of cyclohexanone oxime to e-caprolactam. The catalysts were thoroughly characterized by X-ray diffraction (XRD), sorption analysis, energy dispersive X-ray analysis (EDAX) and Raman spectroscopy. The acidities of the catalysts were estimated by ammonia temperature programmed desorption (NH3-TPD) and Fourier transform infrared studies of adsorbed pyridine (pyridine-FTIR). The optimum temperature for the Beckmann rearrangement was 350 degrees C. Using WOx/SBA-15(20) under the vapor-phase reaction conditions [temperature =350 degrees C. WHSV = 0.6 h(-1), oxime concentration = 2.5% (w/w) in MeOH] gave 79% cyclohexanone oxime conversion with 93%, E-caprolactam selectivity. The epsilon-caprolactam selectivity was found to be dependent on temperature and space velocity. A correlation has been made between the rearrangement activity and acidity and the structural properties of the catalysts. (C) 2010 Elsevier B.V. All rights reserved.