화학공학소재연구정보센터
Advanced Functional Materials, Vol.19, No.21, 3450-3455, 2009
High-Density Periodically Ordered Magnetic Cobalt Ferrite Nanodot Arrays by Template-Assisted Pulsed Laser Deposition
A novel nanopatterning method using pulsed laser deposition through an ultrathin anodic aluminium oxide (AAO) membrane mask is proposed to synthesize well-ordered nanodot arrays of magnetic CoFe2O4 that feature a wide range of applications like sensors, drug delivery, and data storage. This technique allows the adjustment of the array dimension from similar to 35 to similar to 300 nm in diameter and similar to 65 to similar to 500 nm in inter-dot distance. The dot density can be as high as 0.21 Terabit in.(-2) The microstructure of the nanodots is characterized by SEM, TEM, and XRD and the magnetic properties are confirmed by well-defined magnetic force microscopy contrasts and by hysteresis loops recorded by a superconducting quantum interference device. Moreover, the high stability of the AAO mask enables the epitaxial growth of nanodots at a temperature as high as 550 degrees C. The epitaxial dots demonstrate unique complex magnetic domains such as bubble and stripe domains, which are switchable by external magnetic fields. This patterning method creates opportunities for studying novel physics in oxide nanomagnets and may find applications in spintronic devices.