Solid-State Electronics, Vol.54, No.1, 22-27, 2010
A comparative study of photoconductivity and carrier transport in a-Si:H p-i-n solar cells with different back contacts
Effects of different back contacts (Al, Cr, ZnO/Ag, Ag) have been measured on hydrogenated amorphous silicon (a-Si:H) p-i-n solar cell performances and are interpreted in terms of changing recombination kinetics. Dc and frequency-resolved photocurrent measurements in a-Si:H p-i-n solar cells have been carried out experimentally. In particular, the J-V characteristics in the dark and light, the external quantum efficiency spectra, the intensity-, temperature-, bias voltage- and frequency-dependence of photocurrent were obtained. Fill factor (FF) values were determined from J-V characteristics for p-i-n cells with different back contacts under various illumination levels. The exponent nu in the power-law relationship, I-ph alpha G(nu), between generating flux density and photocurrent were determined at different bias voltages (dc) and modulation frequencies. The activation energies were obtained from the temperature-dependence of photocurrent measurements. The integrated external quantum efficiencies were calculated from the spectral photoresponse distributions under reverse bias conditions. The modulation-frequency effects on spectral distributions were also investigated. The results were compared for all cells which have different back contacts and excitation intensity. (C) 2009 Elsevier Ltd. All rights reserved.
Keywords:a-Si:H p-i-n solar cells;Back reflectors;Photocurrent;Quantum efficiency;Recombination;Trapping