화학공학소재연구정보센터
Solid State Ionics, Vol.179, No.27-32, 1575-1578, 2008
Performance of tubular solid oxide fuel cell assembled with plasma-sprayed Sc2O3-ZrO2 electrolyte
Ni-Al2O3 cermet supported tubular solid oxide fuel cell (SOFC) was fabricated by thermal spraying. The anode, electrolyte and cathode were deposited by plasma spraying and the Ni-Al2O3 Cermet support was deposited by flame spraying to aim at reducing manufacturing cost. The test cell was assembled employing scandia stabilized zirconia (ScSZ) and yttria stabilized zirconia (YSZ) deposits as the electrolyte and influence of electrolytic Ohmic polarization on cell's performance was investigated. The results showed that the maximum output power density increased through reducing the electrolyte thickness and increasing the electrical conductivity of electrolyte. The maximum output power density reached 0.89 W/cm(2) with ScSZ electrolyte of 40 mu m thick at 1000 degrees C in comparison of 0.76 W/cm(2) obtained with YSZ electrolyte. The present results clearly revealed that the controlling polarization was electrode polarization for the plasma-sprayed single cell assembled with a thin APS ScSZ electrolyte of 40 pm thick. This fact indicates that the design and preparation of effective electrode in the SOFC assembled using thin electrolyte are more important to improve cell performance. (C) 2008 Elsevier B.V. All rights reserved.