In a solvent extraction screening study, several beta-branched alcohols in the 14-20 carbons range show improved extractive performance to recover ethanol from aqueous solutions compared to commonly studied solvents such as oleyl alcohol and 1-dodecanol. These beta-branched alcohols were selected for screening based on extrapolation of results in earlier work with lower molecular weight aliphatic alcohol solvents, that indicated higher separation factors should be realized when hydroxyl position is mid-chain, and there is branching. Solvent toxicity to a commercial yeast commonly used in fuel ethanol production also was evaluated for these as well as several lower molecular weight alcohols. For the alcohols studied, those containing 12 or fewer carbons were toxic or inhibitory to the yeast; those containing 14 or more carbons were non-toxic and non-inhibitory. Published by Elsevier B.V.