We propose to analyse power law shear stress relaxation modulus observed at the sol-gel transition (SGT) in many gelling systems in terms of fractional calculus. We show that the critical gel (gel at SGT) can be associated to a single fractional element and the gel in the post-SGT state to a fractional Kelvin-Voigt model. In this case, it is possible to give a physical interpretation to the fractional derivative order. It is associated to the power law exponent of the shear modulus related to the fractal dimension of the critical gel. A preliminary experimental application to silica alkoxide-based systems is given.