Synthesis and characterization of trans-Mo(CO)(4)(p-C5NH4SO3Na)(2)

Suarez T; Fontal B; Zambrano G; Reyes M; Bellandi F; Contreras RR; Diaz JC; Cancines P; Fonseca Y; Romero I

Reaction Kinetics and Catalysis Letters, Vol.94, No.1, 21-26, 2008

DOI10.1007/s11144-008-5308-4 Export Citation

Synthesis and characterization of trans-Mo(CO)(4)(p-C5NH4SO3Na)(2)

Suarez T, Fontal B, Zambrano G, Reyes M, Bellandi F, Contreras RR, Diaz JC, Cancines P, Fonseca Y, Romero I

Reaction between MO(CO)(6) and p-C5NH4SO3Na (1:2 (Mo: p-C5NH4SO3Na) stoichiometric ratio) gave the trans-Mo(CO)(4)(p-C5NH4SO3Na)(2) complex, (1), in 80% yield. Complex (1) has been characterized by FTIR, H-1 and C-13 NMR spectroscopy. Complex (1) has most likely an idealized D-4h geometry with trails N-bound p-C5NH4SO3Na ligands.

Keywords:molybdenum;pyridine-p-sulphonate;carbonyl complexes